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dc.contributor.authorChakraborty, Anindita
dc.contributor.authorMaji, Tapas Kumar
dc.identifier.citationChakraborty, A; Maji, TK, Mg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption properties. APL Materials 2014, 2 (12), 124107
dc.identifier.citationAPL Materialsen_US
dc.descriptionOpen Accessen_US
dc.description.abstractNanocrystals of Mg-MOF-74 have been immobilized into the mesopores of SBA-15 rods to fabricate Mg-MOF-74@SBA-15 hybrid materials. To furnish such composites, a relatively simple synthetic strategy has been adopted by direct dispersion of the metal-organic framework (MOF) precursors in SBA-15 matrix to prepare the hybrid materials in situ. The hybrid materials have been characterized using powder X-ray diffraction and several spectroscopic and microscopic techniques, which suggest growth of the MOF nanocrystals inside the SBA-15 mesopores and the composites exhibit characteristics of both the components. N-2 adsorption isotherms at 77 K reveal that the composites contain additional mesopores, compared to only micropores of pristine MOF nanocrystals. In addition to such combination of both micro and mesoporosity, the composites also demonstrate significant CO2 adsorption at room temperature. (C) 2014 Author(s).en_US
dc.publisherAmerican Institute of Physicsen_US
dc.rights@American Institute of Physics, 2014en_US
dc.subjectNanoscience & Nanotechnologyen_US
dc.subjectMaterials Scienceen_US
dc.subjectApplied Physicsen_US
dc.subjectMetal-Organic Frameworksen_US
dc.subjectMesoporous Silicaen_US
dc.titleMg-MOF-74@SBA-15 hybrids: Synthesis, characterization, and adsorption propertiesen_US
Appears in Collections:Research Articles (Tapas Kumar Maji)

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