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Title: | A planar Cu2+ (S = 1/2) kagome network pillared by 1,2-bis(4-pyridyl) ethane with interesting magnetic properties |
Authors: | Kanoo, Prakash Madhu, C Mostafa, Golam Maji, Tapas Kumar Sundaresan, A Pati, Swapan K Rao, C N R |
Keywords: | Terpyridinophane Aza Receptor Molecular-Structure Frustrated Magnets Carbon-Dioxide Co2 Fixation Complexes Lattice Copper(Ii) Series Order |
Issue Date: | 2009 |
Publisher: | Royal Society Chemistry |
Citation: | Dalton Transactions (26), 5062–5064 (2009) |
Abstract: | The reaction of Cu(ClO4)2·6H2O and 1,2-bis(4-pyridyl)ethane (bpe) in basic aqueous solution yields a 3D compound, {[Cu3(CO3)2(bpe)3]·2ClO4}n (1) through the atmospheric fixation of CO2 composing Cu(CO3) kagomé layers pillared by the bpe linker that exhibit weak antiferromagnetic interaction in the kagomé layer and interlayer ferromagnetic coupling at low temperature. |
URI: | https://libjncir.jncasr.ac.in/xmlui/10572/424 |
Other Identifiers: | 1477-9226 |
Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
File | Description | Size | Format | |
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S No 25 2009 Dalton Trans (Commun) 5062-5064.pdf | 1.39 MB | Adobe PDF | View/Open |
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