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https://libjncir.jncasr.ac.in/xmlui/handle/10572/443| Title: | Solvothermal Synthesis of a Layered Open-Framework Chlorocadmium Oxalate, Cd2(C2O4)0.5Cl3NaCl·4H2O |
| Authors: | Vaidhyanathan, R Natarajan, Srinivasan Rao, C N R |
| Keywords: | materials science cadmium solvothermal synthesis metathesis Hydrothermal Synthesis X-Ray Crystal-Structure Cadmium Oxalates Chemistry Units Phosphates Clusters Channels Behavior |
| Issue Date: | May-2003 |
| Publisher: | WILEY-VCH Verlag GmbH |
| Citation: | European Journal Of Inorganic Chemistry (9), 1675-1680 (2003) |
| Abstract: | The metathesis reaction between CdCl2.2H(2)O and sodium oxalate in n-hexanol under solvothermal conditions yields a hybrid compound of formula Cd-2(C2O4)(0.5)Cl3NaCl.4H(2)O, It consists of one-dimensional chains formed by Cd and Cl atoms, containing mu(2)(Cl) and mu(3)(Cl) bridges, and cross-linked by oxalate units to give a layered structure. The Na+ ions and water molecules occupy the interlamellar spaces. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003). |
| Description: | Restricted Access |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/443 |
| Other Identifiers: | 1434-1948 |
| Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| sl.no.16.2003.Eur. J. Inorg. Chem., 1675-1680.pdf Restricted Access | 187.58 kB | Adobe PDF | View/Open Request a copy |
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