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dc.contributor.authorBehera, J N-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-02-21T09:49:33Z-
dc.date.available2012-02-21T09:49:33Z-
dc.date.issued2006-11-13-
dc.identifier0020-1669en_US
dc.identifier.citationInorganic Chemistry 45(23), 9475-9479 (2006)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/482-
dc.descriptionRestricted Accessen_US
dc.description.abstractAn organically templated iron(II) sulfate of the composition [H3N(CH2)(2)NH2(CH2)(2)(NH3](4)[(Fe9F18)-F-II(SO4)(6)], 9H(2)O with a distorted Kagome structure has been synthesized under solvothermal conditions in the presence of diethylenetriamine. The distortion of the hexagonal bronze structure comes from the presence of two different types of connectivity between the FeF4O2 octahedra and the sulfate tetrahedra. This compound exhibits magnetic properties different from those of an Fe(II) compound with a perfect Kagome structure and is a canted antiferromagnet at low temperatures.en_US
dc.description.urihttp://dx.doi.org/10.1021/ic061457yen_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2006 American Chemical Societyen_US
dc.subjectLatticeen_US
dc.subjectAntiferromagneten_US
dc.subjectJarositesen_US
dc.subjectCompounden_US
dc.titleSynthesis and Magnetic Properties of an Amine-Templated Fe2+ (S=2) Sulfate with a Distorted Kagome Structureen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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