1. JNCiR :: JNCASR Institutional Repository
  2. Prof. C.N.R. Rao's Publications
  3. Research Papers (Prof. C.N.R. Rao)
Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/513
Full metadata record
DC FieldValueLanguage
dc.contributor.authorBehera, J N-
dc.contributor.authorGopalkrishnan, K V-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-02-29T11:26:20Z-
dc.date.available2012-02-29T11:26:20Z-
dc.date.issued2004-04-19-
dc.identifier0020-1669en_US
dc.identifier.citationInorganic Chemistry 43(8), 2636-2642 (2004)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/513-
dc.descriptionRestricted Accessen_US
dc.description.abstractTwo organically templated nickel sulfates of the compositions [C4N2H12][Ni3F2(SO4)(3)(H2O)(2)] (I) and [C4N2H12][Ni2F4-(SO4)H2O] (II) with open architectures have been synthesized under hydro/solvothermal conditions in the presence of piperazine. I has a layered structure formed by sinusoidal chains comprising hexameric units, whereas II has a three-dimensional structure with 10-membered channels. The layered Ni(II) sulfate, I, is ferrimagnetic, exhibiting hysteresis at low temperatures. The three-dimensional Ni(II) sulfate, II, is essentially paramagnetic. We have also obtained layered compounds isostructural with I containing other amines.en_US
dc.description.urihttp://dx.doi.org/10.1021/ic035488uen_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2004 American Chemical Societyen_US
dc.subjectCrystal-Structureen_US
dc.subjectMetal Selenitesen_US
dc.subjectIron Sulfatesen_US
dc.subjectRing Channelsen_US
dc.subjectPhosphateen_US
dc.subjectNetworksen_US
dc.subjectKagomeen_US
dc.subject3den_US
dc.titleSynthesis, Structure, and Magnetic Properties of Amine-Templated Open-Framework Nickel(II) Sulfatesen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

Files in This Item:
File Description SizeFormat 
sl.no.41.2004.Inorg. Chem. 43, 2636-2642.pdf
  Restricted Access		559.18 kBAdobe PDFView/Open Request a copy
Show simple item record


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.