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dc.contributor.authorRao, C N R-
dc.contributor.authorSampathkumaran, E V-
dc.contributor.authorNagarajan, R-
dc.contributor.authorPaul, Geo-
dc.contributor.authorBehera, J N-
dc.contributor.authorChoudhury, Amitava-
dc.date.accessioned2012-03-01T06:37:49Z-
dc.date.available2012-03-01T06:37:49Z-
dc.date.issued2004-04-20-
dc.identifier0897-4756en_US
dc.identifier.citationChemistry Of Materials 16(8), 1441-1446 (2004)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/517-
dc.descriptionRestricted Accessen_US
dc.description.abstractAn amine-templated iron(II) sulfate of the composition [H3N(CH2)(6)NH3] [(Fe1.5F3)-F-II(SO4)].0.5H(2)O, 1, representing an example of a Kagome lattice with Fe in the +2 state, has been synthesized under solvothermal conditions. Having determined the structure by single-crystal X-ray diffraction, the oxidation state of iron was established by Mossbauer spectroscopy. The magnetic properties of the Fe(II) Kagome compound are rather unusual in that it undergoes ferrimagnetic ordering below 19 K and does not exhibit spin-glass freezing.en_US
dc.description.urihttp://dx.doi.org/10.1021/cm035304+en_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2004 American Chemical Societyen_US
dc.subjectBond-Valence Parametersen_US
dc.subjectAntiferromagneten_US
dc.subjectSpinen_US
dc.subjectJarositesen_US
dc.subjectNetworksen_US
dc.titleSynthesis, Structure, and the Unusual Magnetic Properties of an Amine-Templated Iron(II) Sulfate Possessing the Kagome Latticeen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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