A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space

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DC Field	Value	Language
dc.contributor.author	Jayaraman, Krishnamoorthy	-
dc.contributor.author	Choudhury, Amitava	-
dc.contributor.author	Vaidhyanathan, Ramanathan	-
dc.contributor.author	Rao, C N R	-
dc.date.accessioned	2012-03-02T10:44:54Z	-
dc.date.available	2012-03-02T10:44:54Z	-
dc.date.issued	2001-09	-
dc.identifier	1144-0546	en_US
dc.identifier.citation	New Journal Of Chemistry 25(9), 1199-1202 (2001)	en_US
dc.identifier.uri	https://libjncir.jncasr.ac.in/xmlui/10572/532	-
dc.description.abstract	Reaction between CdCl2.H2O and NaH2PO4.H2O Under hydrothermal conditions gives rise to a new cadmium chlorophosphate of the formula Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)] I. This material crystallizes in the orthorhombic system with space group Fmm2(no. 42). I has macroanionic layers of [Cd4Cl3(HPO4)(2)(H2PO4)(4)](3-) with Na+ ions in the interlamellar space. The discovery of such compounds suggests that metathetic reactions carried out under hydrothermal conditions may provide a novel route for the synthesis of new open-framework structures.	en_US
dc.description.uri	http://dx.doi.org/10.1039/B103278J	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.rights	© 2001 The Royal Society of Chemistry	en_US
dc.subject	Frameworks Mil-N	en_US
dc.subject	Crystal-Structure	en_US
dc.subject	Phosphates	en_US
dc.subject	Series	en_US
dc.title	A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space	en_US
dc.type	Article	en_US
Appears in Collections:	Research Papers (Prof. C.N.R. Rao)

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