A zinc phosphate oxalate with phosphate layers pillared by the oxalate units

Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/535

Title:	A zinc phosphate oxalate with phosphate layers pillared by the oxalate units
Authors:	Neeraj, S Natarajan, Srinivasan Rao, C N R
Keywords:	coordination chemistry hydrothermal synthesis structural studies X-ray diffraction X-ray powder diffraction zinc Phosphatooxalate Chains
Issue Date:	2001
Publisher:	Royal Society of Chemistry
Citation:	Journal Of The Chemical Society-Dalton Transactions (3), 289-291 (2001)
Abstract:	An open-framework phosphate oxalate of zinc, of composition [NH3(CH2)(3)NH3][Zn-6(PO4)(4)(C2O4)], 1, has been synthesized, for the first time, employing hydrothermal methods in the presence of ethylenediamine. The structure comprises a network of Zn(1)O-5, Zn(2)O-4, Zn(3)O-5 polyhedra and PO4 tetrahedra connected through their vertices forming neutral layers bridged by the oxalate units, giving one-dimensional channels. The presence of Zn in tetrahedral, trigonal-bipyramidal and square-pyramidal coordinations, and the formation of neutral layers, are noteworthy features.
URI:	https://libjncir.jncasr.ac.in/xmlui/10572/535
Other Identifiers:	1472-7773
Appears in Collections:	Research Papers (Prof. C.N.R. Rao)

Files in This Item:

File	Description	Size	Format
sl.no.24.2001.J. Chem. Soc., Dalton Trans., 289-291.pdf		860.15 kB	Adobe PDF	View/Open

DSpace JSPUI