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dc.contributor.authorChoudhury, Amitava-
dc.contributor.authorNeeraj, S-
dc.contributor.authorNatarajan, Srinivasan-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-03-14T09:07:53Z-
dc.date.available2012-03-14T09:07:53Z-
dc.date.issued2002-04-07-
dc.identifier1472-7773en_US
dc.identifier.citationJournal Of The Chemical Society-Dalton Transactions (7), 1535-1538 (2002)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/618-
dc.description.abstractA novel zincoborate, Zn(H2O)B2O4.xH(2)O (xapproximate to0.12), I, with open architecture has been synthesized hydrothermally. The 3-dimensional structure is built up of Zn6B12O24 clusters formed by the capping of the polycyclic borate anion, B12O2412-, by Zn3O3 clusters. The open-framework structure of I has one-dimensional 8-membered channels wherein the water molecules reside. Formation of trimeric Zn3O3 clusters as well as the presence of boron in dual coordination, both triangular and tetrahedral, are important structural features of this new zincoborate.en_US
dc.description.urihttp://dx.doi.org/10.1039/b108047ben_US
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rights© 2002 The Royal Society of Chemistryen_US
dc.subjectHydrothermal Synthesisen_US
dc.subjectSystemen_US
dc.titleAn open-framework zincoborate formed by Zn6B12O24 clustersen_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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