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Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/692
Title: An open-framework iron phosphate with large voids, exhibiting spin-crossover
Authors: Choudhury, Amitava
Natarajan, Srinivasan
Rao, C N R
Keywords: Hydrothermal Synthesis
Magnetic-Properties
Crystal-Structure
Issue Date: 21-Jul-1999
Publisher: Royal Society of Chemistry
Citation: Chemical Communications (14), 1305-1306 (1999)
Abstract: A novel iron phosphate, [(C4N3H16)(C4N3H15)](5+)-[Fe5F4(H2PO4)(HPO4)(3)(PO4)(3)](5-). H2O, consisting of a Fe-O/F-Fe network crosslinked by PO4 groups is shown to possess unusually large elliptical voids of 24 T atoms (T = Fe, P) and to exhibit a gradual low- to high-spin transformation.
URI: https://libjncir.jncasr.ac.in/xmlui/10572/692
Other Identifiers: 1359-7345
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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