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https://libjncir.jncasr.ac.in/xmlui/handle/10572/741| Title: | An ultraviolet photoelectron spectroscopic study of BF3–donor complexes |
| Authors: | Pradeep, T Sreekanth, C S Rao, C N R |
| Keywords: | Photoelectron Spectroscopy Boron Fluorides Donors Acceptors Adducts Water Methanol Ethyl Ether Methyl Compounds Organic Nitrogen Compounds Dissociation Energy Molecular Clusters Complexes Hydrogen Sulfides Nitric Oxide |
| Issue Date: | 1-Apr-1989 |
| Publisher: | American Institute of Physics |
| Citation: | Journal of Chemical Physics 90(9), 4704-4708 (1989) |
| Abstract: | He i spectra of strong n–v type adducts of BF3 with H2O, CH3OH, (C2H5)2O, and CH3CN as well as of weak complexes of BF3 with NO and H2S are reported along with assignments based on MO calculations. The energy of the fluorine orbitals of BF3 is shown to be shifted in proportion to the strength of the donor–acceptor interaction. BF3 seems to form a contact pair with CS2. |
| Description: | Restricted Access |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/741 |
| Other Identifiers: | 0021-9606 |
| Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| sl.no35.1989.Journal of Chemical Physics 90(9), 4704-4708 ().pdf Restricted Access | 304.21 kB | Adobe PDF | View/Open Request a copy |
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