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DC Field | Value | Language |
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dc.contributor.author | Kovatcheva, D | - |
dc.contributor.author | Hewat, A W | - |
dc.contributor.author | Rangavittal, N | - |
dc.contributor.author | Manivannan, V | - |
dc.contributor.author | Row, T N Guru | - |
dc.contributor.author | Rao, C N R | - |
dc.date.accessioned | 2012-10-31T10:21:26Z | - |
dc.date.available | 2012-10-31T10:21:26Z | - |
dc.date.issued | 1991-02-15 | - |
dc.identifier | 0921-4534 | en_US |
dc.identifier.citation | Physica C : Superconductivity 173(5-6), 444–452 (1991) | en_US |
dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/890 | - |
dc.description | Restricted Access | en_US |
dc.description.abstract | The structures of TlSr(2−x)LaxCuO(5+δ), with x=0.5, 0.75 and 1, and Tl.5Pb0.5Sr2CuO(5+δ) have been examined with X-ray and neutron powder Rietveld refinement. They are isostructural (P4/mmm) with the corresponding thallium-barium cuprate having one Cu-O layer with Cu3+ ions in octahedral coordination with oxygen (structure type 1201). The influence of cation substitution and disorder on the structure and superconducting properties of these phases have been investigated. La3+ substitution for Sr2+ stabilises the structure and reduces Cu3+, permitting superconductivity, while Pb2+ substitution for Tl3+ only stabilises the structure, without reducing Cu3+. | en_US |
dc.description.uri | http://dx.doi.org/10.1016/0921-4534(91)90746-L | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Science BV | en_US |
dc.rights | © 1991 Elsevier Science BV | en_US |
dc.subject | Temperature Superconductor La1.85sr0.15cuo4 | en_US |
dc.subject | Crystal-Structure | en_US |
dc.subject | Tc | en_US |
dc.subject | Transition | en_US |
dc.subject | Valence | en_US |
dc.title | An X-ray and neutron diffraction study of cation substituted TlSr2CuO5 | en_US |
dc.type | Article | en_US |
Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
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1991.35.pdf Restricted Access | 668.21 kB | Adobe PDF | View/Open Request a copy |
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