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dc.contributor.authorKovatcheva, D-
dc.contributor.authorHewat, A W-
dc.contributor.authorRangavittal, N-
dc.contributor.authorManivannan, V-
dc.contributor.authorRow, T N Guru-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-10-31T10:21:26Z-
dc.date.available2012-10-31T10:21:26Z-
dc.date.issued1991-02-15-
dc.identifier0921-4534en_US
dc.identifier.citationPhysica C : Superconductivity 173(5-6), 444–452 (1991)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/890-
dc.descriptionRestricted Accessen_US
dc.description.abstractThe structures of TlSr(2−x)LaxCuO(5+δ), with x=0.5, 0.75 and 1, and Tl.5Pb0.5Sr2CuO(5+δ) have been examined with X-ray and neutron powder Rietveld refinement. They are isostructural (P4/mmm) with the corresponding thallium-barium cuprate having one Cu-O layer with Cu3+ ions in octahedral coordination with oxygen (structure type 1201). The influence of cation substitution and disorder on the structure and superconducting properties of these phases have been investigated. La3+ substitution for Sr2+ stabilises the structure and reduces Cu3+, permitting superconductivity, while Pb2+ substitution for Tl3+ only stabilises the structure, without reducing Cu3+.en_US
dc.description.urihttp://dx.doi.org/10.1016/0921-4534(91)90746-Len_US
dc.language.isoenen_US
dc.publisherElsevier Science BVen_US
dc.rights© 1991 Elsevier Science BVen_US
dc.subjectTemperature Superconductor La1.85sr0.15cuo4en_US
dc.subjectCrystal-Structureen_US
dc.subjectTcen_US
dc.subjectTransitionen_US
dc.subjectValenceen_US
dc.titleAn X-ray and neutron diffraction study of cation substituted TlSr2CuO5en_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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