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Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/923
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dc.contributor.authorAyyappan, S-
dc.contributor.authorBu, X-
dc.contributor.authorCheetham, A K-
dc.contributor.authorRao, C N R-
dc.date.accessioned2012-11-06T11:07:44Z-
dc.date.available2012-11-06T11:07:44Z-
dc.date.issued1998-11-
dc.identifier0897-4756en_US
dc.identifier.citationChemistry Of Materials 10(11), 3308-3310 (1998)en_US
dc.identifier.urihttps://libjncir.jncasr.ac.in/xmlui/10572/923-
dc.descriptionRestricted Accessen_US
dc.description.abstractA chiral open-framework tin phosphate structure, [CN3H6][Sn4P3O12], has been obtained by using an achiral structure-directing agent, guanidine. The structures of both enantiomorphs have been determined: tetragonal, space groups P4(3) (No. 78) and P4(1) (No. 76), a = 8.8881(1) Angstrom, c = 20.6029(4) Angstrom, V = 1627.59 (4) Angstrom(3), Z = 4, M = 819.76. The framework, which is composed of puckered 6-membered (Sn3P3O6) and 12-membered (Sn6P6O12) rings, accommodates the organic cation in a tortuous chiral channel.en_US
dc.description.urihttp://dx.doi.org/10.1021/cm980559men_US
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 1998 American Chemical Societyen_US
dc.subjectExperimental studyen_US
dc.subjectChemical preparationen_US
dc.subjectHydrothermal synthesisen_US
dc.subjectMolecular sieveen_US
dc.subjectOrganic cationen_US
dc.subjectGuanidinium compoundsen_US
dc.subjectTin complexen_US
dc.subjectPhosphato complexen_US
dc.subjectAnionic complexen_US
dc.subjectHydrogen bonden_US
dc.subjectX ray diffractionen_US
dc.subjectCrystalline structureen_US
dc.subjectPolynuclear complexen_US
dc.subjectChannel structureen_US
dc.subjectInorganic compounden_US
dc.titleSynthesis And Structural Characterization Of A Chiral Open-Framework Tin(Ii) Phosphate, [Cn3h6][Sn4p3o12] (Guan-Snpo)en_US
dc.typeArticleen_US
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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