Novel supramolecular organizations in melamine complexes with 4,4'-bipyridyl and silver nitrate

Abstract

Complexes of melamine with 4,4'-bipyridyl and AgNO3 having compositions, C10H8N2:0.5(C3H6N6):H2O and [Ag(C3H6N6)]NO3, respectively, have been prepared for the first time. A crystallographic investigation has shown unique hydrogen bonding patterns in the two systems. The melamine-4,4'-bipyridyl complex shows a supramolecular organization wherein hydrogen bonding between melamine and water molecules results in tapes. The tapes are connected by hydrogen bonding to 4,4'-bipyridyl giving rise to a rectangular box. In the melamine-AgNO3 complex, the melamine molecules are bound to Ag+ ions forming N-Ag-N chains, giving rise to a helix. The helices are held together by interchain hydrogen bonds. (C) 2001 Elsevier Science B.V. All rights reserved.