Please use this identifier to cite or link to this item: https://libjncir.jncasr.ac.in/xmlui/handle/10572/995
Title: Electronic Structures of Perovskite Oxides of Transition Metals of the Type LaMO3 (M = Ti-Ni) as Revealed by MSXα Investigations
Authors: Sarma, D D
Santra, A K
Rao, C N R
Keywords: Spectroscopy
Issue Date: Jun-1994
Publisher: Academic Press Inc JNL-Comp Subscriptions
Citation: Journal Of Solid State Chemistry 110(2), 393-396 (1994)
Abstract: Systematic investigations of the electronic structures of MO9-6 (M = Ti-Ni) clusters, as in the LaMO3 type perovskite oxides, have been carried out by employing the multiple-scattering Xα (MSXα) method. The crystal-field splitting of the metal d level is found to increase, while the oxygen-to-metal charge-transfer energy decreases across the transition metal series. Systematic trends are also seen in the mixing (covalency) between the metal d and the oxygen 2p orbitals in the series.
Description: Note. Restricted Access.
URI: https://libjncir.jncasr.ac.in/xmlui/10572/995
Other Identifiers: 0022-4596
Appears in Collections:Research Papers (Prof. C.N.R. Rao)

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