Please use this identifier to cite or link to this item:
https://libjncir.jncasr.ac.in/xmlui/handle/10572/995
Title: | Electronic Structures of Perovskite Oxides of Transition Metals of the Type LaMO3 (M = Ti-Ni) as Revealed by MSXα Investigations |
Authors: | Sarma, D D Santra, A K Rao, C N R |
Keywords: | Spectroscopy |
Issue Date: | Jun-1994 |
Publisher: | Academic Press Inc JNL-Comp Subscriptions |
Citation: | Journal Of Solid State Chemistry 110(2), 393-396 (1994) |
Abstract: | Systematic investigations of the electronic structures of MO9-6 (M = Ti-Ni) clusters, as in the LaMO3 type perovskite oxides, have been carried out by employing the multiple-scattering Xα (MSXα) method. The crystal-field splitting of the metal d level is found to increase, while the oxygen-to-metal charge-transfer energy decreases across the transition metal series. Systematic trends are also seen in the mixing (covalency) between the metal d and the oxygen 2p orbitals in the series. |
Description: | Note. Restricted Access. |
URI: | https://libjncir.jncasr.ac.in/xmlui/10572/995 |
Other Identifiers: | 0022-4596 |
Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
sl.no19.1994..pdf Restricted Access | 186.31 kB | Adobe PDF | View/Open Request a copy |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.