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Synthesis and structure of [C3N2H5][Cu(H2PO4)(2)Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate
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| dc.contributor.author | Neeraj, S
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| dc.contributor.author | Loiseau, T
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| dc.contributor.author | Rao, C N R
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| dc.contributor.author | Cheetham, A K
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| dc.date.accessioned | 2014-08-13T23:48:22Z | |
| dc.date.available | 2014-08-13T23:48:22Z | |
| dc.date.issued | 2004-10 | |
| dc.identifier | 1293-2558 | en_US |
| dc.identifier.citation | Solid State Sciences 6(10), 1169-1173 (2004) | en_US |
| dc.identifier.uri | https://libjncir.jncasr.ac.in/xmlui/10572/1396 | |
| dc.description | Restricted Access | en_US |
| dc.description.abstract | A new one-dimensional copper (II) phosphate, [C3N2H5][Cu(H2PO4)(2)Cl](H2O)-H-., I, with pseudo-10-membered channels along the b-axis formed by the hydrogen bonded chains, containing imidazolium ions has been synthesized and characterized by single-crystal X-ray diffraction. The compound being the first example of an organically templated copper (II) phosphate, crystallizes in the monoclinic space group P2(1)/n (No. 14) with a = 8.9998(14) Angstrom, b = 7.0189(11) Angstrom, c = 18.986(3) Angstrom; beta = 102.964(3)degrees; V = 1168.8(3) Angstrom(3); Z = 4. The copper chlorophosphate chains in I are topologically similar to those observed in fornacite and vauquelinite. (C) 2004 Elsevier SAS. All rights reserved | en_US |
| dc.description.uri | http://dx.doi.org/10.1016/j.solidstatesciences.2004.05.007 | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science BV | en_US |
| dc.rights | © 2004 Elsevier SAS | en_US |
| dc.subject | Open-Framework | en_US |
| dc.subject | Magnetic-Properties | en_US |
| dc.subject | Crystal-Structure | en_US |
| dc.subject | Metal Phosphates | en_US |
| dc.subject | Hydrothermal Synthesis | en_US |
| dc.subject | Open Architectures | en_US |
| dc.subject | Cobalt Phosphate | en_US |
| dc.subject | Zinc Phosphates | en_US |
| dc.subject | Sodalite | en_US |
| dc.subject | C2h10n2 | en_US |
| dc.title | Synthesis and structure of [C3N2H5][Cu(H2PO4)(2)Cl]·H2O with a chain structure: the first example of an organically templated copper (II) phosphate | en_US |
| dc.type | Article | en_US |
