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https://libjncir.jncasr.ac.in/xmlui/handle/10572/464| Title: | Three-Dimensional Organically Templated Open-Framework Transition Metal Selenites |
| Authors: | Choudhury, Amitava Kumar D, Udaya Rao, C N R |
| Keywords: | crystal growth iron magnetic properties mesoporous materials selenium Iron Phosphate Crystal-Structure Hydrothermal Synthesis Microporous Compounds Magnetic-Properties Networks Form Fef3 |
| Issue Date: | 2002 |
| Publisher: | WILEY-VCH Verlag GmbH |
| Citation: | Angewandte Chemie-International Edition 41(1), 158-161 (2002) |
| Abstract: | One dimensional channels are formed in the three-dimensional open-framework iron selenite [C4N2H12]0.5[Fe2F3(SeO3)2] (I), which was synthesized hydrothermally from FeCl3⋅6 H2O, HF, and SeO2 in the presence of the organic amine piperazine. The same inorganic framework was also obtained with the amines diethylenetetramine, 1,3-diaminopropane, and ethylenediamine. Compound I displays unusual magnetic frustration behavior that is attributed to the tetrahedral geometry. |
| Description: | Restricted Access |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/464 |
| Other Identifiers: | 1433-7851 |
| Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| sl.no.10.2002.Angew. Chem. Int. Ed. 2002, 41(1),158_ftp.pdf Restricted Access | 155.3 kB | Adobe PDF | View/Open Request a copy |
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