A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space

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Title:	A layered chlorophosphate, Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)], containing Na+ ions in the interlamellar space
Authors:	Jayaraman, Krishnamoorthy Choudhury, Amitava Vaidhyanathan, Ramanathan Rao, C N R
Keywords:	Frameworks Mil-N Crystal-Structure Phosphates Series
Issue Date:	Sep-2001
Publisher:	Royal Society of Chemistry
Citation:	New Journal Of Chemistry 25(9), 1199-1202 (2001)
Abstract:	Reaction between CdCl2.H2O and NaH2PO4.H2O Under hydrothermal conditions gives rise to a new cadmium chlorophosphate of the formula Na-3[Cd4Cl3(HPO4)(2)(H2PO4)(4)] I. This material crystallizes in the orthorhombic system with space group Fmm2(no. 42). I has macroanionic layers of [Cd4Cl3(HPO4)(2)(H2PO4)(4)](3-) with Na+ ions in the interlamellar space. The discovery of such compounds suggests that metathetic reactions carried out under hydrothermal conditions may provide a novel route for the synthesis of new open-framework structures.
URI:	https://libjncir.jncasr.ac.in/xmlui/10572/532
Other Identifiers:	1144-0546
Appears in Collections:	Research Papers (Prof. C.N.R. Rao)

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