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https://libjncir.jncasr.ac.in/xmlui/handle/10572/618| Title: | An open-framework zincoborate formed by Zn6B12O24 clusters |
| Authors: | Choudhury, Amitava Neeraj, S Natarajan, Srinivasan Rao, C N R |
| Keywords: | Hydrothermal Synthesis System |
| Issue Date: | 7-Apr-2002 |
| Publisher: | Royal Society of Chemistry |
| Citation: | Journal Of The Chemical Society-Dalton Transactions (7), 1535-1538 (2002) |
| Abstract: | A novel zincoborate, Zn(H2O)B2O4.xH(2)O (xapproximate to0.12), I, with open architecture has been synthesized hydrothermally. The 3-dimensional structure is built up of Zn6B12O24 clusters formed by the capping of the polycyclic borate anion, B12O2412-, by Zn3O3 clusters. The open-framework structure of I has one-dimensional 8-membered channels wherein the water molecules reside. Formation of trimeric Zn3O3 clusters as well as the presence of boron in dual coordination, both triangular and tetrahedral, are important structural features of this new zincoborate. |
| URI: | https://libjncir.jncasr.ac.in/xmlui/10572/618 |
| Other Identifiers: | 1472-7773 |
| Appears in Collections: | Research Papers (Prof. C.N.R. Rao) |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| sl.no.38.2002,.J. Chem. Soc., Dalton Trans.,(7) 1535-1538.pdf | 177.97 kB | Adobe PDF | View/Open |
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